Kuld, S. et al. Quantifying the promotion of Cu catalysts by ZnO for methanol synthesis. Science 352, 969–974 (2016).
Sushkevich, V. L., Palagin, D., Ranocchiari, M. & Van Bokhoven, J. A. Selective anaerobic oxidation of methane enables direct synthesis of methanol. Science 356, 523–527 (2017).
Ravi, M., Ranocchiari, M. & van Bokhoven, J. A. The direct catalytic oxidation of methane to methanol—A critical assessment. Angew. Chem. Int. Ed. 56, 16464–16483 (2017).
Narsimhan, K., Iyoki, K., Dinh, K. & Román-Leshkov, Y. Catalytic oxidation of methane into methanol over copper-exchanged zeolites with oxygen at low temperature. ACS Cent. Sci. 2, 424–429 (2016).
Dinh, K. T. et al. Continuous partial oxidation of methane to methanol catalyzed by diffusion-paired copper dimers in copper-exchanged zeolites. J. Am. Chem. Soc. 141, 11641–11650 (2019).
Jin, Z. et al. Hydrophobic zeolite modification for in situ peroxide formation in methane oxidation to methanol. Science 367, 193–197 (2020).
Williams, C. et al. Selective oxidation of methane to methanol using supported AuPd catalysts prepared by stabilizer-free sol-immobilization. ACS Catal. 8, 2567–2576 (2018).
Shi, C. et al. Direct conversion of methane to methanol and formaldehyde over a double-layered catalyst bed in the presence of steam. Chem. Commun. https://doi.org/10.1039/cc9960000663 (1996).
Almond, M. J. et al. Carbonyl sulfide (OCS) as a sulfur-containing precursor in MOCVD: A study of mixtures of Me2Cd and OCS in the gas and solid phases and their use in MOCVD. J. Mater. Chem. 6, 1639 (1996).
Kondratenko, E. V. et al. Catalysis Science & technology perspective methane conversion into different hydrocarbons or oxygenates: Current status and future perspectives in catalyst development and reactor operation. Catal. Sci. Technol. 7, 19–33 (2014).
Latimer, A. A., Kakekhani, A., Kulkarni, A. R. & Nørskov, J. K. Direct methane to methanol: The selectivity-conversion limit and design strategies. ACS Catal. 8, 6894–6907 (2018).
Brown, M. J. & Parkyns, N. D. Progress in the partial oxidation of methane to methanol and formaldehyde. Catal. Today 8, 305–335 (1991).
Feng, N. et al. Efficient and selective photocatalytic CH4 conversion to CH3 OH with O2 by controlling overoxidation on TiO2. Nat. Commun. https://doi.org/10.1038/s41467-021-24912-0 (2021).
Trinh, Q. T., Banerjee, A., Yang, Y. & Mushrif, S. H. Sub-surface boron-doped copper for methane activation and coupling: First-principles investigation of the structure, activity, and selectivity of the catalyst. J. Phys. Chem. C 121, 1099–1112 (2017).
Collins, N. A., Debenedetti, P. G. & Sundaresan, S. Disproportionation of toluene over ZSM–5 under near-critical conditions. AIChE J. 34, 1211–1214 (1988).
Theyssen, N., Hou, Z. & Leitner, W. Selective oxidation of alkanes with molecular oxygen and acetaldehyde in compressed (supercritical) carbon dioxide as reaction medium. Chem. A Eur. J. 12, 3401–3409 (2006).
Brock, E. E., Oshima, Y., Savage, P. E. & Barker, J. R. Kinetics and mechanism of methanol oxidation in supercritical water. J. Phys. Chem. 100, 15834–15842 (1996).
Savage, P. E., Li, R. & Santini, J. T. Methane to methanol in supercritical water. J. Supercrit. Fluids 7, 135–144 (1994).
Savage, P. E., Rovira, J., Stylski, N. & Martino, C. J. Oxidation kinetics for methane/methanol mixtures in supercritical water. J. Supercrit. Fluids 17, 155–170 (2000).
Savage, P. E. Organic chemical reactions in supercritical water. Chem. Rev. 99, 603–621 (1999).
Ferrieri, R. A., Garcia, I., Fowler, J. S. & Wolf, A. P. Investigations of acetonitrile solvent cluster formation in supercritical carbon dioxide, and its impact on microscale syntheses of carbon-11-labeled radiotracers for PET. Nucl. Med. Biol. 26, 443–454 (1999).
Jessop, P. G. & Subramaniam, B. Gas-expanded liquids. Chem. Rev. 107, 2666–2694 (2007).
Lee, J. H. & Foster, N. R. Direct partial oxidation of methane to methanol in supercritical water. J. Supercrit. Fluids 9, 99–105 (1996).
Webley, P. A. & Tester, J. W. Fundamental kinetics of methane oxidation in supercritical water. Energy Fuels 5, 411–419 (2002).
Dixon, C. N. & Abraham, M. A. Conversion of methane to methanol by catalytic supercritical water oxidation. J. Supercrit. Fluids 5, 269–273 (1992).
Zhang, X. et al. Methanol conversion on borocarbonitride catalysts: Identification and quantification of active sites. Sci. Adv. 6, 5778–5802 (2020).
Wang, G., Zhang, X., Yan, Y., Huang, X. & Xie, Z. New insight into structural transformations of borocarbonitride in oxidative dehydrogenation of propane. Appl. Catal. A Gen. 628, 118402 (2021).
Li, S., Zhang, X., Huang, X., Wu, S. & Xie, Z. Identification of active sites of B/N co-doped nanocarbons in selective oxidation of benzyl alcohol. J. Colloid Interface Sci. 608, 2801–2808 (2022).
Wang, Y. et al. Methane activation over a boron nitride catalyst driven by: In situ formed molecular water. Catal. Sci. Technol. 8, 2051–2055 (2018).
Grant, J. T. et al. Selective oxidative dehydrogenation of propane to propene using boron nitride catalysts. Science 354, 1570–1573 (2016).
Venegas, J. M. et al. Selective oxidation of n-butane and isobutane catalyzed by boron nitride. ChemCatChem 9, 2118–2127 (2017).
Tian, J. et al. Direct conversion of methane to formaldehyde and CO on B2 O3 catalysts. Nat. Commun. https://doi.org/10.1038/s41467-020-19517-y (2020).
Love, A. M. et al. Probing the transformation of boron nitride catalysts under oxidative dehydrogenation conditions. J. Am. Chem. Soc. 141, 182 (2019).
Turner, G. L., Smith, K. A., Kirkpatrick, R. J. & Oldfield, E. Boron-11 nuclear magnetic resonance spectroscopic study of borate and borosilicate minerals and a borosilicate glass. J. Magn. Reson. 67, 544–550 (1986).
Kroeker, S. & Stebbins, J. F. Three-coordinated boron-11 chemical shifts in borates. Inorg. Chem. 40, 6239–6246 (2001).
Gervais, C. et al. 11B and 15N solid state NMR investigation of a boron nitride preceramic polymer prepared by ammonolysis of borazine. J. Eur. Ceram. Soc. 25, 129–135 (2005).
Huang, C., Liu, Q., Fan, W. & Qiu, X. Boron nitride encapsulated copper nanoparticles: A facile one-step synthesis and their effect on thermal decomposition of ammonium perchlorate. Sci. Rep. 5, 16736 (2015).
Ci, L. et al. Atomic layers of hybridized boron nitride and graphene domains. Nat. Mater. 9, 430. https://doi.org/10.1038/NMAT2711 (2010).
Huang, C., Ye, W., Liu, Q. & Qiu, X. Dispersed Cu2O octahedrons on h-BN nanosheets for p-nitrophenol reduction. ACS Appl. Mater. Interfaces 6, 14469–14476 (2014).
Pilli, A. et al. In situ XPS study of low temperature atomic layer deposition of B2 O3 films on Si using BCl3 and H2O precursors articles you may be interested in in situ XPS study of low temperature atomic layer deposition of B2 O3 films on Si using BCl3 and H2O precursors. J. Vac. Sci. Technol. A 36, 61503 (2018).
Gesser, H. D. & Prakash, C. B. Chemical reviews the direct conversion of methane to methanol by controlled oxidation. Chem. Rev. 85, 235 (1985).
Sato, T., Watanabe, M., Smith, R. L., Adschiri, T. & Arai, K. Analysis of the density effect on partial oxidation of methane in supercritical water. J. Supercrit. Fluids 28, 69–77 (2004).
Gagliardi, L. G., Castells, C. B., Ràfols, C., Rosés, M. & Bosch, E. Static dielectric constants of acetonitrile/water mixtures at different temperatures and Debye-Hückel A and a 0 B parameters for activity coefficients. J. Chem. Eng. Data 52, 1103–1107 (2007).
Hong Wei Xiang. The Corresponding-States Principle and Its Practice (Elsevier, 2005).
Srinivasan, K. R. & Kay, R. L. The pressure dependence of the dielectric constant and density of acetonitrile at three temperatures. J. Solut. Chem. 6, 357–367 (1977).
Brennecke, J. F. & Eckert, C. A. Phase equilibria for supercritical fluid process design. AIChE J. 35, 1409–1427 (1989).
Kim, S. & Johnston, K. P. Clustering in supercritical fluid mixtures. AIChE J. 33, 1603–1611 (1987).
Ikushima, Y., Saito, N. & Arai, M. Supercritical carbon dioxide as reaction medium: Examination of its solvent effects in the near-critical region. J. Phys. Chem. 96, 2293–2297 (1992).
Petrenko, V. E., Gurina, D. L. & Antipova, M. L. Structure of supercritical water: The concept of critical isotherm as a percolation threshold. Russ. J. Phys. Chem. B 6, 899–906 (2012).
Gribov, L. A., Novakov, I. A., Pavlyuchko, A. I., Korolkov, V. V. & Orlinson, B. S. Spectroscopic calculation of CH bond dissociation energies for aliphatic nitriles. J. Struct. Chem. 45, 771–777 (2004).
Shi, L. et al. Progress in selective oxidative dehydrogenation of light alkanes to olefins promoted by boron nitride catalysts. Chem. Commun. 54, 10936–10946 (2018).
Venegas, J. M. et al. Why boron nitride is such a selective catalyst for the oxidative dehydrogenation of propane. Angew. Chem. Int. Ed. 59, 16527–16535 (2020).
Grant, J. T. et al. Boron and boron-containing catalysts for the oxidative dehydrogenation of propane. ChemCatChem 9, 3623–3626 (2017).
Zakaria, Z. & Kamarudin, S. K. Direct conversion technologies of methane to methanol: An overview. Renew. Sustain. Energy Rev. 65, 250–261 (2016).
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